Printing inks containing oxidatively crosslinkable urethane resins

Oxidatively crosslinking essentially isocyanate-free urethane resins, obtainable by reacting A) 100 parts by weight of an ester of (a1) an aliphatic C3-C8-alcohol having three or more hydroxyl groups and (a2) an unsaturated C8-C40-fatty acid and (a3) if required, an aliphatic or aromatic polycarboxy...

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Hauptverfasser: LAWRENZ, DIRK, PRANTL, BERNHARD, WALZ, ROLF
Format: Patent
Sprache:eng
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Zusammenfassung:Oxidatively crosslinking essentially isocyanate-free urethane resins, obtainable by reacting A) 100 parts by weight of an ester of (a1) an aliphatic C3-C8-alcohol having three or more hydroxyl groups and (a2) an unsaturated C8-C40-fatty acid and (a3) if required, an aliphatic or aromatic polycarboxylic acid of 4 to 20 carbon atoms or an anhydride thereof, in amounts of up to 60% by weight, based on the fatty acid a2), the ester containing sufficient free hydroxyl groups to correspond to an OH number of 50-150 mg of KOH/g, with B) (b1) 3-120 parts by weight of C5-C15-polyhydroxycarboxylic acids having two or more hydroxyl groups and (b2) 10-100 parts by weight of an aliphatic or cycloaliphatic polyisocyanate or a mixture thereof, at 50 DEG -150 DEG C. in the presence of a nonpolar solvent which is inert to isocyanates, are suitable for use as printing ink components.