Process for production of an ethanol solution of the ethyl or butyl half-ester of a copolymer of maleic anhydride and methyl vinyl ether

There is described a process for the production of an ethanol solution of an ethyl or butyl half-ester copolymer of maleic anhydride and a methyl vinyl ether which comprises: (a) copolymerizing the monomers in acetone as solvent by simultaneously feeding molten maleic anhydride, a molar excess of me...

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Bibliographische Detailangaben
Hauptverfasser: ZAMORA, JOHN N, CARLIN, ALAN J, TAZI, MOHAMMED
Format: Patent
Sprache:eng
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Zusammenfassung:There is described a process for the production of an ethanol solution of an ethyl or butyl half-ester copolymer of maleic anhydride and a methyl vinyl ether which comprises: (a) copolymerizing the monomers in acetone as solvent by simultaneously feeding molten maleic anhydride, a molar excess of methyl vinyl ether, and a solution of a free radical initiator in acetone, into a reactor precharged with acetone, at about 68 DEG -85 DEG C., preferably 70 DEG -80 DEG C.; (b) esterifying the acetone solution of said copolymer with ethanol or butanol; and then (c) solvent exchanging ethanol for acetone by continuously injecting vapors of ethanol at about 85 DEG -95 DEG C. into said copolymer solution while simultaneously distilling out acetone therefrom at atmospheric pressure.