PROCESS FOR SELECTIVE COMPLEXOMETRIC ANALYSIS OF N-PHOSPHOROMETHYL-GLYCINE, N-CARBOXYMETHYL-N-PHOSPHONOMETHYL-GLYCINE AND N,N-BISPHOSPHONO-METHYL-GLYCINE
A process is provided for the quantitative selective complexometric analysis of a sample. First and second aliquot parts of a sample containing N-phosphonomethyl-glycine, N-carboxymethyl-N-phosphonomethyl-glycine or N,N-bis-phosphonomethyl-glycine; or N-phosphonomethyl-glycine and N,N-bis-phosphonom...
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Zusammenfassung: | A process is provided for the quantitative selective complexometric analysis of a sample. First and second aliquot parts of a sample containing N-phosphonomethyl-glycine, N-carboxymethyl-N-phosphonomethyl-glycine or N,N-bis-phosphonomethyl-glycine; or N-phosphonomethyl-glycine and N,N-bis-phosphonomethyl-glycine; or N-phosphonomethyl-glycine and N-carboxymethyl-N-phosphonomethyl-glycine are taken. The first aliquot part is titrated with a bismuth volumetric solution at a Ph=1.8-2.5 in the presence of a methylethymol blue indicator. The second aliquot part is titrated with a copper volumetric solution at a Ph=8-10 in the presence of a murexide indicator. Two end point values are obtained and compared. The difference between these two values result in the determination of the content of N-phosphonomethyl-glycine in the sample. |
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