PROCESS FOR PREPARATION OF CONDENSED ALCOHOLS BY ALKOXIDE CATALYSTS

PROCESS FOR PREPARATION OF CONDENSED ALCOHOLS BY ALKOXIDE CATALYSTS

Condensed dimer alcohols, also known as Guerbet alcohols, are prepared using metal alkoxide as the catalyst by reacting alcohol with saturated or unsaturated aldehyde or allyl alcohol, or mixtures thereof, at 100 DEG C-220 DEG C and removing water as it is formed during the reaction. Dimer alcohols...

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Bibliographische Detailangaben
Hauptverfasser: MCLAUGHLIN, MARK L, YOUNG, DAVID A, JUNG, JOHN A
Format: Patent
Sprache:eng
Schlagworte:
ACYCLIC OR CARBOCYCLIC COMPOUNDS
APPARATUS THEREFOR
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
GENERAL METHODS OF ORGANIC CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
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Zusammenfassung:Condensed dimer alcohols, also known as Guerbet alcohols, are prepared using metal alkoxide as the catalyst by reacting alcohol with saturated or unsaturated aldehyde or allyl alcohol, or mixtures thereof, at 100 DEG C-220 DEG C and removing water as it is formed during the reaction. Dimer alcohols are prepared in high yields without the need for a transition metal catalyst.