Platinum containing pullulan derivatives and compositions containing the same

Platinum containing pullulan derivatives and compositions containing the same

Pullulan platinum complexes are new, in which the pullulan bears active sites of formula (Ia), (Ib), (Ic) or (Id): and one hydrogen atom of some or all of these active sites is replaced by a group of formula (IIa) or (IIb): (where L1 and L2 are each ammonia or a unidentate amine, or together are a b...

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Bibliographische Detailangaben
Hauptverfasser: MORI, FUMIO, NISHIDA, TAKASHI, KAWAI, KOUICHIRO, TASHIRO, TAZUKO, MIKI, SHUJI, OKADA, MASAFUMI, EBASHI, IWAO, TSUKAGOSHI, SHIGERU
Format: Patent
Sprache:eng
Schlagworte:
CHEMISTRY
COMPOSITIONS BASED THEREON
DERIVATIVES THEREOF
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
POLYSACCHARIDES
THEIR PREPARATION OR CHEMICAL WORKING-UP
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Beschreibung
Zusammenfassung:Pullulan platinum complexes are new, in which the pullulan bears active sites of formula (Ia), (Ib), (Ic) or (Id): and one hydrogen atom of some or all of these active sites is replaced by a group of formula (IIa) or (IIb): (where L1 and L2 are each ammonia or a unidentate amine, or together are a bidentate amine; Y is an anionic ligand); or in the case of (Ic) two hydrogen atoms may be replaced by a group of formula (IV); or the hydrogen atom of two adjacent (Id) may be replaced by (IV). Prepn is by sulphation, sulphonation, phosphorylation or carboxylation of pullulan, followed by reaction with a platinum compound of formula (III): (where X1 and X2 are nitrato, or one is nitrato and the other is hydroxo or sulphato).