Optically active iridium complexes and their use

Optically active iridium complexes of the formula in which R is methyl and R1 is a hydrocarbon radical having at least one chiral C atom or a hydrocarbon radical containing at least one hetero atom and having at least one chiral C atom; or R is a hydrogen atom and R1 is 1,2-diphenylethyl or a 5-memb...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Hauptverfasser:	KASCHIG, JUERGEN
Format:	Patent
Sprache:	eng
Schlagworte:	ACYCLIC OR CARBOCYCLIC COMPOUNDS ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM APPARATUS THEREFOR CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY GENERAL METHODS OF ORGANIC CHEMISTRY HETEROCYCLIC COMPOUNDS METALLURGY ORGANIC CHEMISTRY PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL THEIR RELEVANT APPARATUS TRANSPORTING
Online-Zugang:	Volltext bestellen
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	Optically active iridium complexes of the formula in which R is methyl and R1 is a hydrocarbon radical having at least one chiral C atom or a hydrocarbon radical containing at least one hetero atom and having at least one chiral C atom; or R is a hydrogen atom and R1 is 1,2-diphenylethyl or a 5-membered or 6-membered cycloaliphatic or cycloheteroaliphatic radical having at least two chiral C atoms and a phenyl group or alkyl group in the alpha -position, X(-) is an anion of a monobasic inorganic or organic acid and Y and Z are each ethylene, or Y and Z together represent an open-chain or cyclic diene which has 6 to 10 C atoms and whose diene groups are bonded via 1 or 2 C atoms. They are suitable as enantioselective, homogeneous catalysts for the transfer hydrogenation of, in particular, prochiral ketones with secondary alcohols.