Process and apparatus for decontaminating exhaust gas from a fusion reactor fuel cycle of exhaust gas components containing chemically bonded tritium and/or deuterium
Process for decontaminating an exhaust gas from a fusion reactor fuel cycle of exhaust gas components containing at least one heavy hydrogen isotope selected from tritium and deuterium in compound form, the compound form being ammonia and hydrocarbon, the exhaust gas containing CO and hydrogen isoto...
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Zusammenfassung: | Process for decontaminating an exhaust gas from a fusion reactor fuel cycle of exhaust gas components containing at least one heavy hydrogen isotope selected from tritium and deuterium in compound form, the compound form being ammonia and hydrocarbon, the exhaust gas containing CO and hydrogen isotopes and in which the at least one heavy hydrogen isotope is liberated from its compound, separated out from the exhaust gas and fed back into the fuel cycle, comprising (a) carrying out a catalytic oxidation reaction at a temperature of from 200 DEG C. to 250 DEG C., to oxidize the exhaust gas components, without changing the ammonia, as follows: CO to CO2, hydrocarbon to CO2+water, and the hydrogen isotopes to water, (b) bringing the gas admixture resulting from step (a) into contact with a metal bed at a temperature in the range of 200 DEG C. to 400 DEG C. to selectively transform the water into hydrogen isotopes and to remove O2, (c) bringing the gas admixture resulting from step (b) ino contact with a hot membrane made of palladium or a palladium-silver alloy to crack the ammonia at a temperature of 400 DEG C. to 450 DEG C., and to pass all liberated hydrogen isotopes through the membrane to separate out the liberated hydrogen isotopes from the flow of the remaining exhaust gas, and (d) discharging the remaining decontaminated exhaust gas into the surrounding air. |
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