Process for preparing poly(aryl ether)ketones using a sodium carbonate/organic acid salt catalyst

Process for preparing poly(aryl ether)ketones using a sodium carbonate/organic acid salt catalyst

Described herein is a novel process for the preparation of poly(aryl ether ketones). The process comprises reacting an activated dihalobenzenoid compound with a diphenol and/or in self-condensing a halophenol whose halogen atom is activated towards nucleophilic substitution reactions. The polymeriza...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: MATZNER, MARKUS, WINSLOW, PAUL A
Format: Patent
Sprache:eng
Schlagworte:
CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
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Beschreibung
Zusammenfassung:Described herein is a novel process for the preparation of poly(aryl ether ketones). The process comprises reacting an activated dihalobenzenoid compound with a diphenol and/or in self-condensing a halophenol whose halogen atom is activated towards nucleophilic substitution reactions. The polymerizations are performed at high temperatures, in an aprotic solvent, and in the presence of a base. The base comprises sodium carbonate or bicarbonate and a potassium, rubidium or cesium salt of an organic acid.