Process for purifying aluminum with sodium

Aluminum contaminated with at least one of the metals of the groups II b, III a, IV a and V a of the periodic table of elements is purified by means of sodium applied in liquid extraction in a separating column in the temperature range between the melting point of the aluminum or aluminum alloys and the boiling point of sodium. The pre-heated sodium is introduced into the separating column from a circuit having a heat exchanger, solids precipitator, pump and storage tank, in quantities at least 5 times greater than the mass of contaminating metal. The sodium flows countercurrent to the contaminated aluminum which is also introduced into the separating column. The purified aluminum containing a small residual amount of contaminating metal and a sodium content not exceeding 500 ppm is removed from the separating column. The sodium containing a low concentration of contaminating metal is returned to the circuit.