Secondary batteries containing room-temperature molten 1,2,3-trialkylimidazolium halide non-aqueous electrolyte

Batteries and especially secondary batteries employing an anode comprising aluminum and a molten, non-aqueous electrolyte containing admixtures of aluminum halide and 1,2,3-trialkylimidazolium halides having the formula TimX: wherein R1, R2 and R3 are independently alkyl groups of 1 to 12 carbons an...

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Hauptverfasser: SHACKLETTE, LAWRENCE W, TOTH, JAMES E, GIFFORD, PAUL R, PALMISANO, JAMES B, CHANCE, RONALD R
Format: Patent
Sprache:eng
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Zusammenfassung:Batteries and especially secondary batteries employing an anode comprising aluminum and a molten, non-aqueous electrolyte containing admixtures of aluminum halide and 1,2,3-trialkylimidazolium halides having the formula TimX: wherein R1, R2 and R3 are independently alkyl groups of 1 to 12 carbons and X is independently halide or mixtures of halides, e.g., chloride and/or bromide are disclosed. The molar ratio of aluminum hereinafter denoted by Al, to trialkylimidalozium, hereinafter denoted by Tim, in the electrolyte, may be varied over a wide range so as to make the molten electrolyte composition acidic and as such the electrolyte is useful in batteries, especially secondary batteries employing aluminum anodes and a variety of cathodes.