Direct conversion of a polymerization reaction catalyzed by a Ziegler-type catalyst into one catalyzed by a chromium-based catalyst

A method of converting a continuous olefin polymerization reaction catalyzed by a Ziegler-type catalyst into one catalyzed by a chromium-based catalyst, without the need of emptying and recharging the polymerization reactor, by adding a hydroxyl-containing compound to the reactor containing the Zieg...

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Bibliographische Detailangaben
Hauptverfasser: WILLIAMS, GARY H, KAROL, FREDERICK J
Format: Patent
Sprache:eng
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Zusammenfassung:A method of converting a continuous olefin polymerization reaction catalyzed by a Ziegler-type catalyst into one catalyzed by a chromium-based catalyst, without the need of emptying and recharging the polymerization reactor, by adding a hydroxyl-containing compound to the reactor containing the Ziegler-type catalyst to interact with such catalyst before the chromium-based catalyst is introduced into the reactor.