High density ion exchange resins

High density, ion exchange resins having excellent integrity are prepared from cross-linked, aromatic polymers which have been halogenated in the presence of an organic liquid having a sufficiently high dielectric constant to prevent substantial halogenation of the polymer backbone such as various o...

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Bibliographische Detailangaben
Hauptverfasser:	RALEY, JR., CHARLES F, HUSSER, EDWARD R
Format:	Patent
Sprache:	eng
Schlagworte:	CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY FERROUS OR NON-FERROUS ALLOYS METALLURGY PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL PRETREATMENT OF RAW MATERIALS PRODUCTION AND REFINING OF METALS THEIR RELEVANT APPARATUS TRANSPORTING TREATMENT OF ALLOYS OR NON-FERROUS METALS
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Beschreibung
Zusammenfassung:	High density, ion exchange resins having excellent integrity are prepared from cross-linked, aromatic polymers which have been halogenated in the presence of an organic liquid having a sufficiently high dielectric constant to prevent substantial halogenation of the polymer backbone such as various organic nucleophiles having a free electron pair associated with a nonhalogen atom, e.g., ethanol or dimethylformamide. For example, a cross-linked polystyrene which has been brominated in methylene chloride containing a small amount of ethanol can subsequently be chloromethylated and aminated to form a high density anion exchange resin useful in removing anions from thick slurries such as those employed in uranium recovery.