Hydrogenation of fluoroacids with rhenium-fluorided alumina catalyst

A fluoroacid is continuously hydrogenated to a corresponding alcohol by contact with a catalyst comprising at least one of rhenium and a hydrogen reducible rhenium compound supported on a fluorided alumina catalyst support. In one embodiment perfluorobutyric acid is catalytically reduced to 2,2,3,3,...

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Hauptverfasser: ASHE, JR., DECEASED, BENEDICT H, HUDSON, PAUL S, JOHNSON, MARVIN M, NOWACK, GERHARD P
Format: Patent
Sprache:eng
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Zusammenfassung:A fluoroacid is continuously hydrogenated to a corresponding alcohol by contact with a catalyst comprising at least one of rhenium and a hydrogen reducible rhenium compound supported on a fluorided alumina catalyst support. In one embodiment perfluorobutyric acid is catalytically reduced to 2,2,3,3,4,4,4-heptafluoro n-butanol employing a fluorided activated alumina impregnated with perrhenic acid.