Layered or amorphous acyclic organometallic inorganic polymers

Inorganic compounds which contain pendant organic functional groups are prepared by the reaction of an acid of the formula [(HO)2OZOx]kR, in which Z is a pentavalent metal, X is 0 or 1, k is 1 or 2, and R is an acyclic organo group, with a tetravalent metal ion. The compounds are insoluble in the re...

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Hauptverfasser: DINES, MARTIN B, DIGIACOMO, PETER M
Format: Patent
Sprache:eng
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Zusammenfassung:Inorganic compounds which contain pendant organic functional groups are prepared by the reaction of an acid of the formula [(HO)2OZOx]kR, in which Z is a pentavalent metal, X is 0 or 1, k is 1 or 2, and R is an acyclic organo group, with a tetravalent metal ion. The compounds are insoluble in the reaction medium, exist in a layered crystalline to amorphous form, and have the formula M(O3ZOxR)n, in which M is the tetravalent metal and n is 1 or 2. One use for the compounds is as selective sorbents.