Selective dealkylation of 4-tertiary-alkyl-2,5-xylenol

A method is described for the selective dealkylation of 4-tertiary-alkyl-2,5-xylenol while it is admixed with 6-tertiary-alkyl-2,4-xylenol by contacting the mixture of alkylated xylenols with a polymer-bound sulfonic acid catalyst at temperatures of 60 DEG C. or less and pressures of from about 0.5...

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Bibliographische Detailangaben
Hauptverfasser: DODD, JOHN R
Format: Patent
Sprache:eng
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Zusammenfassung:A method is described for the selective dealkylation of 4-tertiary-alkyl-2,5-xylenol while it is admixed with 6-tertiary-alkyl-2,4-xylenol by contacting the mixture of alkylated xylenols with a polymer-bound sulfonic acid catalyst at temperatures of 60 DEG C. or less and pressures of from about 0.5 to 5 atmospheres. The method is useful in separating 2,4-/2,5-xylenol mixtures.