Dechlorination of haloethanes using ethylene

A haloethane is dechlorinated by reacting in the gaseous phase a haloethane selected from CCl2FFCClF2, CClF2CClF2 and CCl2FCCl2F with ethylene in the presence of a transition metal catalyst selected from iron, nickel, vanadium and chromium oxides, chlorides and fluorides and recovering a perhaloethy...

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Bibliographische Detailangaben
Hauptverfasser: NYCHKA, HENRY R, EIBECK, RICHARD E
Format: Patent
Sprache:eng
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Zusammenfassung:A haloethane is dechlorinated by reacting in the gaseous phase a haloethane selected from CCl2FFCClF2, CClF2CClF2 and CCl2FCCl2F with ethylene in the presence of a transition metal catalyst selected from iron, nickel, vanadium and chromium oxides, chlorides and fluorides and recovering a perhaloethylene and vinyl chloride. Perhaloethylenes are used as monomers for halogenated polymers. Vinyl chloride is also a widely used monomer.