Process for the chlorination of toluene

In the process for the nuclear chlorination of alkylbenzenes, such as toluene, in the presence of a para-directing catalyst system comprising a substantially iron-free Lewis acid catalyst and thianthrene compound co-catalyst, wherein the reaction mixture is in contact with iron or an alloy thereof,...

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Bibliographische Detailangaben
Hauptverfasser: BUCKHOLTZ, HARRY E, BOSE, ARUN C
Format: Patent
Sprache:eng
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Zusammenfassung:In the process for the nuclear chlorination of alkylbenzenes, such as toluene, in the presence of a para-directing catalyst system comprising a substantially iron-free Lewis acid catalyst and thianthrene compound co-catalyst, wherein the reaction mixture is in contact with iron or an alloy thereof, the para-directing effect of the catalyst system is improved by the addition of an amide.