Acid-catalyzed decomposition of aliphatic hydroperoxides

Acid-catalyzed decomposition of aliphatic hydroperoxides

Tertiary aliphatic hydroperoxides and peroxides in the presence of a highly concentrated acid catalyst are converted to a mixture of ketones and alcohols in substantially quantitative yields. The corresponding secondary aliphatic hydroperoxides yield product mixtures of alcohols, ketones and aldehyd...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: DENO, NORMAN C, TURNER, JOHN O
Format: Patent
Sprache:eng
Schlagworte:
ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
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Beschreibung
Zusammenfassung:Tertiary aliphatic hydroperoxides and peroxides in the presence of a highly concentrated acid catalyst are converted to a mixture of ketones and alcohols in substantially quantitative yields. The corresponding secondary aliphatic hydroperoxides yield product mixtures of alcohols, ketones and aldehydes in varying proportions, depending upon the acid concentration employed.