Novel process for the production of methylol

The reaction of isobutylene and methylal to form a mixture 1,3-dimethoxy-3-methyl butane and 4-methoxy-2-methylbutene-1 and rearrangement of the same to yield isoprene and methanol is disclosed herein. The isobutylene and methylal may be obtained by the oxidation of isobutane to form t-butylhydroper...

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Bibliographische Detailangaben
Hauptverfasser: TURNER, JOHN O
Format: Patent
Sprache:eng
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Zusammenfassung:The reaction of isobutylene and methylal to form a mixture 1,3-dimethoxy-3-methyl butane and 4-methoxy-2-methylbutene-1 and rearrangement of the same to yield isoprene and methanol is disclosed herein. The isobutylene and methylal may be obtained by the oxidation of isobutane to form t-butylhydroperoxide, followed by rearrangement of the hydroperoxide to yield methylal and t-butyl alcohol and dehydration of the alcohol to produce isobutylene.