Cobalt modified iron oxides

Acicular, gamma, cobalt-modified, iron oxide, magnetic particles produced by: coprecipitation of about 25 percent of the ferrous and cobaltous ions in a slightly alkaline aqueous medium; thereafter oxidize to a slightly acid medium; coprecipitate balance of metallic ions and oxidize; recover the alp...

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Bibliographische Detailangaben
Hauptverfasser: FESSLER, ROBERT GLENN, TRANDELL, ROGER FRANCIS
Format: Patent
Sprache:eng
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Beschreibung
Zusammenfassung:Acicular, gamma, cobalt-modified, iron oxide, magnetic particles produced by: coprecipitation of about 25 percent of the ferrous and cobaltous ions in a slightly alkaline aqueous medium; thereafter oxidize to a slightly acid medium; coprecipitate balance of metallic ions and oxidize; recover the alpha form of cobalt-modified ferric oxide; reduce particles with hydrogen; and, thereafter oxidize to the gamma form, which process is characterized by almost quantative recovery of the cobaltous ion by raising the pH to about 10 of the slurry containing the alpha particles.