Compositions containing heterocyclic compounds and resinous products prepared therefrom
A heat curable composition comprises (1) an ether or an ester of an alcohol of the formula where n is 1 or 2 and (2) an amine having at least two nitrogen bonded hydrogen atoms. The esters (1) generally contain another five-or six-membered ring. Specified compounds (1) are 3,4 - dihydro - 1,2 - pyr...
Gespeichert in:
1. Verfasser: | |
---|---|
Format: | Patent |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext bestellen |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | A heat curable composition comprises (1) an ether or an ester of an alcohol of the formula where n is 1 or 2 and (2) an amine having at least two nitrogen bonded hydrogen atoms. The esters (1) generally contain another five-or six-membered ring. Specified compounds (1) are 3,4 - dihydro - 1,2 - pyranyl - 2 - methyl-3,4 - dihydro - 1,2 - pyran - 2 - carboxylate; 3,4 - dihydro - 1,2 - pyran - 2 - methyl - 2,3-dihydrothiophene - 2 - carboxylate; 3,4 - dihydro - 1,2 - pyran - 2 - methyl - N - methyl-2,3 - dihydropyrrole - 2 - carboxylate; 3,4-dihydro - 1,2 - pyran - 2 - methyl - 2,3 - dihydrofuran - 2 - carboxylate; dimethyldi - (3,4-dihydro - 1,2 - pyran - 2 - methoxy) silane; tri-(3,4 - dihydro - 1,2 - pyran - 2 - methyl) ether. Examples of amines are metaphenylene diamine, methylene dianiline, diaminodiphenylsulphone, triethylenetetramine, di - (hexamethylene) triamine, 1,3 - diamino-(methyl) cyclohexane and 1,3 - diaminocyclohexane. The composition is prepared by mixing the two components together with or without a solvent. Suitable amounts of amine are 0.8 to 1.5 equivalents per ethylenic group adjacent to the heteroatom. Other materials, e.g. fillers, dyes, plasticizers, stabilizers, vinyl resins, tars, pitches, distillate oils and alkyd resins may be added. Resinification is by heating to 90 DEG to 250 DEG C., accelerators or catalysts may be added. Uses.-Laminates, adhesives, mouldings and surface coating compositions. |
---|