alpha-tocopherol dimer and process for its preparation
An a -tocopherol dimer of formula is used as an antioxidant for fats and oils.ALSO:The invention comprises an a -tocopherol dimer of the formula:- and its acetate. The dimer is made by oxidizing a -tocopherol with a water-soluble salt of ferricyanic acid, e.g. the potassium salt, under aqueous alka...
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| creator | NELAN DONALD R |
| description | An a -tocopherol dimer of formula is used as an antioxidant for fats and oils.ALSO:The invention comprises an a -tocopherol dimer of the formula:- and its acetate. The dimer is made by oxidizing a -tocopherol with a water-soluble salt of ferricyanic acid, e.g. the potassium salt, under aqueous alkaline conditions to give an intermediate product of formula:- and reducing this product with a mild reducing agent, e.g. ascorbic acid. The acetate ester may be prepared by treating the a -tocopherol dimer with acetic anhydride and pyridine. The diquinone of the a -tocopherol dimer may be obtained by oxidizing the dimer with ferric chloride and has the formula:- The a -tocopherol dimer may be used as an antioxidant in the stabilization of Vitamin A esters, e.g. Vitamin A palmitate. |
| format | Patent |
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The dimer is made by oxidizing a -tocopherol with a water-soluble salt of ferricyanic acid, e.g. the potassium salt, under aqueous alkaline conditions to give an intermediate product of formula:- <FORM:1012321/C2/2> and reducing this product with a mild reducing agent, e.g. ascorbic acid. The acetate ester may be prepared by treating the a -tocopherol dimer with acetic anhydride and pyridine. The diquinone of the a -tocopherol dimer may be obtained by oxidizing the dimer with ferric chloride and has the formula:- <FORM:1012321/C2/3> The a -tocopherol dimer may be used as an antioxidant in the stabilization of Vitamin A esters, e.g. Vitamin A palmitate.</description><language>eng</language><subject>ANIMAL AND VEGETABLE OILS, FATS, FATTY SUBSTANCES AND WAXES ; CANDLES ; CHEMISTRY ; DETERGENTS ; ESSENTIAL OILS ; FATTY ACIDS THEREFROM ; HETEROCYCLIC COMPOUNDS ; METALLURGY ; ORGANIC CHEMISTRY ; PERFUMES ; PRODUCING (PRESSING, EXTRACTION), REFINING AND PRESERVINGFATS, FATTY SUBSTANCES (e.g. LANOLIN), FATTY OILS AND WAXES,INCLUDING EXTRACTION FROM WASTE MATERIALS</subject><creationdate>1965</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=19650316&DB=EPODOC&CC=US&NR=3173927A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,776,881,25543,76293</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=19650316&DB=EPODOC&CC=US&NR=3173927A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>NELAN DONALD R</creatorcontrib><title>alpha-tocopherol dimer and process for its preparation</title><description>An a -tocopherol dimer of formula <FORM:1012321/C4-C5/1> is used as an antioxidant for fats and oils.ALSO:The invention comprises an a -tocopherol dimer of the formula:-<FORM:1012321/C2/1> and its acetate. The dimer is made by oxidizing a -tocopherol with a water-soluble salt of ferricyanic acid, e.g. the potassium salt, under aqueous alkaline conditions to give an intermediate product of formula:- <FORM:1012321/C2/2> and reducing this product with a mild reducing agent, e.g. ascorbic acid. The acetate ester may be prepared by treating the a -tocopherol dimer with acetic anhydride and pyridine. The diquinone of the a -tocopherol dimer may be obtained by oxidizing the dimer with ferric chloride and has the formula:- <FORM:1012321/C2/3> The a -tocopherol dimer may be used as an antioxidant in the stabilization of Vitamin A esters, e.g. Vitamin A palmitate.</description><subject>ANIMAL AND VEGETABLE OILS, FATS, FATTY SUBSTANCES AND WAXES</subject><subject>CANDLES</subject><subject>CHEMISTRY</subject><subject>DETERGENTS</subject><subject>ESSENTIAL OILS</subject><subject>FATTY ACIDS THEREFROM</subject><subject>HETEROCYCLIC COMPOUNDS</subject><subject>METALLURGY</subject><subject>ORGANIC CHEMISTRY</subject><subject>PERFUMES</subject><subject>PRODUCING (PRESSING, EXTRACTION), REFINING AND PRESERVINGFATS, FATTY SUBSTANCES (e.g. LANOLIN), FATTY OILS AND WAXES,INCLUDING EXTRACTION FROM WASTE MATERIALS</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>1965</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZDBLzCnISNQtyU_OL8hILcrPUUjJzE0tUkjMS1EoKMpPTi0uVkjLL1LILCkG8lMLEosSSzLz83gYWNMSc4pTeaE0N4O8m2uIs4duakF-fGpxQWJyal5qSXxosLGhubGlkbmjMWEVABA7LTg</recordid><startdate>19650316</startdate><enddate>19650316</enddate><creator>NELAN DONALD R</creator><scope>EVB</scope></search><sort><creationdate>19650316</creationdate><title>alpha-tocopherol dimer and process for its preparation</title><author>NELAN DONALD R</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_US3173927A3</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng</language><creationdate>1965</creationdate><topic>ANIMAL AND VEGETABLE OILS, FATS, FATTY SUBSTANCES AND WAXES</topic><topic>CANDLES</topic><topic>CHEMISTRY</topic><topic>DETERGENTS</topic><topic>ESSENTIAL OILS</topic><topic>FATTY ACIDS THEREFROM</topic><topic>HETEROCYCLIC COMPOUNDS</topic><topic>METALLURGY</topic><topic>ORGANIC CHEMISTRY</topic><topic>PERFUMES</topic><topic>PRODUCING (PRESSING, EXTRACTION), REFINING AND PRESERVINGFATS, FATTY SUBSTANCES (e.g. LANOLIN), FATTY OILS AND WAXES,INCLUDING EXTRACTION FROM WASTE MATERIALS</topic><toplevel>online_resources</toplevel><creatorcontrib>NELAN DONALD R</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>NELAN DONALD R</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>alpha-tocopherol dimer and process for its preparation</title><date>1965-03-16</date><risdate>1965</risdate><abstract>An a -tocopherol dimer of formula <FORM:1012321/C4-C5/1> is used as an antioxidant for fats and oils.ALSO:The invention comprises an a -tocopherol dimer of the formula:-<FORM:1012321/C2/1> and its acetate. The dimer is made by oxidizing a -tocopherol with a water-soluble salt of ferricyanic acid, e.g. the potassium salt, under aqueous alkaline conditions to give an intermediate product of formula:- <FORM:1012321/C2/2> and reducing this product with a mild reducing agent, e.g. ascorbic acid. The acetate ester may be prepared by treating the a -tocopherol dimer with acetic anhydride and pyridine. The diquinone of the a -tocopherol dimer may be obtained by oxidizing the dimer with ferric chloride and has the formula:- <FORM:1012321/C2/3> The a -tocopherol dimer may be used as an antioxidant in the stabilization of Vitamin A esters, e.g. Vitamin A palmitate.</abstract><oa>free_for_read</oa></addata></record> |
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| subjects | ANIMAL AND VEGETABLE OILS, FATS, FATTY SUBSTANCES AND WAXES CANDLES CHEMISTRY DETERGENTS ESSENTIAL OILS FATTY ACIDS THEREFROM HETEROCYCLIC COMPOUNDS METALLURGY ORGANIC CHEMISTRY PERFUMES PRODUCING (PRESSING, EXTRACTION), REFINING AND PRESERVINGFATS, FATTY SUBSTANCES (e.g. LANOLIN), FATTY OILS AND WAXES,INCLUDING EXTRACTION FROM WASTE MATERIALS |
| title | alpha-tocopherol dimer and process for its preparation |
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