Lubricating oil additives

866,498. N-vinyl butyrolactam copolymers. ESSO RESEARCH & ENGINEERING CO. May 25, 1959 [Nov. 18, 1958], No. 37033/58. Addition to 808,665. Class 2(6). [Also in Group III] An oil-soluble copolymer of (1) an N-vinyl butyrolactam and (2) an itaconate ester of a C 8 -C 18 alcohol is employed as an o...

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Hauptverfasser: BRYAN JOAN D, AGIUS PETER J. V. J, GARBETT THOMAS A
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Sprache:eng
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Zusammenfassung:866,498. N-vinyl butyrolactam copolymers. ESSO RESEARCH & ENGINEERING CO. May 25, 1959 [Nov. 18, 1958], No. 37033/58. Addition to 808,665. Class 2(6). [Also in Group III] An oil-soluble copolymer of (1) an N-vinyl butyrolactam and (2) an itaconate ester of a C 8 -C 18 alcohol is employed as an oil additive (see Group III). Monomers (1) and (2) may be copolymerized with (3) an ester formed between an unsaturated alcohol and a C 2 -C 6 carboxylic acid. Polymerization may be effected with the aid of catalysts (e.g. benzoyl peroxide or alphaalpha1-azobisisobutyronitrile) or radiation (e.g. ultra-violet, beta or gamma rays). In an example, an N-vinyl pyrrolidone/lauryl itaconate/vinyl acetate copolymer is prepared, using benzoyl peroxide dissolved in dimethyl phthalate as catalyst. For comparison purposes, an N-vinyl pyrrolidone/lauryl fumarate/vinyl acetate copolymer is similarly prepared.