METHOD FOR PREPARING WATER GAS SHIFT CATALYSTS, CATALYSTS AND PROCESS FOR REDUCING CARBON MONOXIDE CONTENT

The present invention relates to HTS catalysts applied in hydrogen or synthesis gas production units, whether in steam reforming, autothermal reforming, dry or gasification reforming, chromium-free, consisting of iron oxide, containing platinum contents between 0.1 to 0.4% w/w, promoted by sodium co...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Hauptverfasser: QUITETE, Cristina Pontes Bittencourt, CARDOSO, Mauri Jose Baldini, BITTENCOURT, Roberto Carlos Pontes
Format: Patent
Sprache:eng
Schlagworte:
Online-Zugang:Volltext bestellen
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The present invention relates to HTS catalysts applied in hydrogen or synthesis gas production units, whether in steam reforming, autothermal reforming, dry or gasification reforming, chromium-free, consisting of iron oxide, containing platinum contents between 0.1 to 0.4% w/w, promoted by sodium contents between 0.1 to 0.3% w/w, and optionally aluminum contents between 5.0 to 6.0% w/w inserted into the crystal lattice of an iron oxide with a hematite (Fe2O3) crystal structure, thus, allowing high activity to be reconciled with excellent resistance to deactivation by exposure to high temperatures. In a second aspect, the present invention provides a carbon monoxide conversion process by bringing said catalyst into contact with a synthesis gas stream, where the maximum bed temperature can be limited by the injection of water or steam next to the feed of CO-containing gas at the reactor inlet.