FABRICATING THREE-DIMENSIONAL SEMICONDUCTOR STRUCTURES

In certain embodiments, a method includes forming, on a substrate by spin-on deposition, a layer stack of alternating layers of first and second carbon-containing materials. The layers of the first carbon-containing material include an agent-generating ingredient for generating a solubility-changing agent in response to an activation trigger. The method includes executing the activation trigger in response to which the solubility-changing agent is generated from the agent-generating ingredient in the layers of the first carbon-containing material and modifies the layers of the first carbon-containing material to be soluble in a developer. The method includes etching first openings through the layer stack, filling the first openings with a third material, etching second openings through the layer stack, removing the layers of the first carbon-containing material from the layer stack by exposing those to the developer, and replacing the layers of the first carbon-containing material with a fourth material.