LOW-THERMAL-SHRINKAGE POLYESTER INDUSTRIAL YARN AND PREPARATION METHOD THEREOF

A low-thermal-shrinkage polyester industrial yarn and preparation method thereof are provided. The low-thermal-shrinkage polyester industrial yarn is prepared by spinning and winding a modified polyester after solid-state polycondensation to increase viscosity. The preparation method of the modified...

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Hauptverfasser: YANG, Damao, SUN, Xiaohua, WANG, Lili, WANG, Shanshui, TANG, Fangming, WANG, Tong, ZHANG, Ye, CHEN, Rui
Format: Patent
Sprache:eng
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Zusammenfassung:A low-thermal-shrinkage polyester industrial yarn and preparation method thereof are provided. The low-thermal-shrinkage polyester industrial yarn is prepared by spinning and winding a modified polyester after solid-state polycondensation to increase viscosity. The preparation method of the modified polyester includes: after uniformly mixing terephthalic acid, ethylene glycol, 2,5-pyridinedicarboxylic acid and copper chloride, successively performing an esterification reaction and a polycondensation reaction to obtain the modified polyester. The polyester segments of the prepared low-thermal-shrinkage polyester industrial yarn comprises a terephthalic acid segment, an ethylene glycol segment and a 2,5-pyridinedicarboxylic acid segment, and 2,5-pyridinedicarboxylic acid segments of different polyester segments are coordinated by Cu2+. The molar ratio of the terephthalic acid segment to the 2,5-pyridinedicarboxylic acid segment is 1:(0.03-0.05). The O atom on a carbonyl group and the N atom on the pyridine of the 2,5-pyridinedicarboxylic acid segment are involved in the coordination.