A POSITIVE ELECTRODE ACTIVE MATERIAL FOR RECHARGEABLE LITHIUM-ION BATTERIES

A positive electrode active material for batteries which comprises Li, M′, and oxygen, wherein M′ comprises: Ni in a content a between 70.0 mol % and 95.0 mol %; Co in a content x between 0.0 mol % and 25.0 mol %; Mn in a content y between 0.0 mol % and 25.0 mol %, a dopant D in a content z between...

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Bibliographische Detailangaben
Hauptverfasser:	PAULSEN, Jens Martin, KIM, JiHye
Format:	Patent
Sprache:	eng
Schlagworte:	BASIC ELECTRIC ELEMENTS CHEMISTRY COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSESC01D OR C01F ELECTRICITY INORGANIC CHEMISTRY METALLURGY PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY
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Beschreibung
Zusammenfassung:	A positive electrode active material for batteries which comprises Li, M′, and oxygen, wherein M′ comprises: Ni in a content a between 70.0 mol % and 95.0 mol %; Co in a content x between 0.0 mol % and 25.0 mol %; Mn in a content y between 0.0 mol % and 25.0 mol %, a dopant D in a content z between 0.0 mol % and 2.0 mol %, Al and B in a total content c between 0.1 mol % and 5.0 mol %, wherein the active material has an Al content AlA and a B content BA, wherein a, x, y, z, c, AlA and BA are measured by ICP, wherein AlA, and BA are expressed as molar fractions compared to the sum of a and x and y, wherein the positive electrode active material, when measured by XPS analysis, shows an average Al fraction AlB and an average B fraction BB, wherein the ratio AlB/AlA>1.0, wherein the ratio BB/BA>1.0, and wherein the positive electrode active material is a single-crystalline powder.