METHOD AND EXTRACTION DEVICE FOR EXTRACTING AND PREPARING BATTERY-GRADE LITHIUM CARBONATE FROM P507 RAFFINATE

Disclosed are a method and device for extracting and preparing battery-grade lithium carbonate from a P507 raffinate. The method comprises steps of impurity adjustment, extraction, purification, reverse extraction, alkalization, crystallization, separation, drying, the impurity adjustment comprises:...

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Hauptverfasser: WANG, Zi, WU, Shanmu, LIU, Zhen, LIU, Xunbing, PENG, Can, ZHOU, Quncheng, OUYANG, Jianjun, DONG, Xiongwu
Format: Patent
Sprache:eng
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Zusammenfassung:Disclosed are a method and device for extracting and preparing battery-grade lithium carbonate from a P507 raffinate. The method comprises steps of impurity adjustment, extraction, purification, reverse extraction, alkalization, crystallization, separation, drying, the impurity adjustment comprises: adjusting a pH value of the P507 raffinate to be 8.5 to 10.5 with lithium hydroxide or alkali, and filtering to obtain a filtrate for later use; the alkalization comprises: heating a lithium solution to 85° C. to 95° C., adding lithium hydroxide or alkali to adjust a pH value to be 9.0 to 13.0, maintaining a temperature at 85° C. to 95° C. and standing for 2 hours to 8 hours, and then filtering to obtain a filtrate for later use; and the crystallization comprises: introducing compressed air into the filtrate after alkalization, evaporating and concentrating at the same time, and discharging and cooling when fine crystals exist in the concentrated solution.