Value Chain Return Process for Spent Polyurethanes by Hydrogenation

Spent polyurethanes are returned to the value chain by hydrogenating the spent polyurethanes in a hydrogen atmosphere in the presence of at least one homogeneous transition metal catalyst complex, wherein the transition metal is selected from metals of groups 7, 8, 9 and 10 of the periodic table of...

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Hauptverfasser: Haedler, Andreas Thomas, Zhou, Wei, Zubar, Viktoriia, Neumann, Paul, Al Batal, Mona, Schaub, Thomas, Schuette, Markus, Hashmi, A. Stephen K
Format: Patent
Sprache:eng
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Zusammenfassung:Spent polyurethanes are returned to the value chain by hydrogenating the spent polyurethanes in a hydrogen atmosphere in the presence of at least one homogeneous transition metal catalyst complex, wherein the transition metal is selected from metals of groups 7, 8, 9 and 10 of the periodic table of elements according to IUPAC, to obtain a polyamine and a polyol. The hydrogenation is carried out at a reaction temperature of at least 120° C. in a non-reducible solvent having a dipole moment of 10-1030 C·m or less.