SPHERE-LIKE SUPER-MACROPOROUS MESOPOROUS MATERIAL AND POLYOLEFIN CATALYST CONTAINING SAME

Disclosed are a spherelike supermacroporous mesoporous material, a polyolefin catalyst, and a preparation method therefor and an olefin polymerization process. The spherelike supermacroporous mesoporous material has a twodimensional hexagonal ordered pore channel structures. The mesoporous material...

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Bibliographische Detailangaben
Hauptverfasser: LIU, Hongmei, WANG, Ruen, LIU, Dongbing, KANG, Yu, LI, Bingyi, LYU, Xinping, GUO, Zifang
Format: Patent
Sprache:eng
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Zusammenfassung:Disclosed are a spherelike supermacroporous mesoporous material, a polyolefin catalyst, and a preparation method therefor and an olefin polymerization process. The spherelike supermacroporous mesoporous material has a twodimensional hexagonal ordered pore channel structures. The mesoporous material has an average pore size of 10 nm to 15 nm, a specific surface area of 300 m2/g to 400 m2/g, and an average particle size of 1 µm to 3 µm, based on the total mass of the mesoporous material. The mass content of water in the mesoporous material is < 1 ppm. The mass content of oxygen in the mesoporous material is < 1 ppm. When a polyolefin catalyst prepared with the mesoporous material as a carrier is used for an olefin polymerization reaction, the a polyolefin product with a narrow molecular weight distribution and a good melt index can be obtained.