PREPARATION METHOD OF GLASSLESS GRAIN-ORIENTED SILICON STEEL AND PRODUCT THEREOF

A preparation method of glassless grain-oriented silicon steel includes the following operations. During a decarburization annealing, a thickness of an oxide film on a surface of strip is 1.5-2.5 μm; an atomic weight ratio of Si element and Fe element in the oxide film satisfies: Si/(Si+Fe)≥0.76; du...

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Hauptverfasser: SONG, Donghe, XIAO, Huiming, HU, Zhiyuan, WANG, Xianhui, GAO, Qian, SUN, Maolin, QI, Jiebin, LIU, Zhaoyue, YOU, Xuechang, ZHAO, Songshan, WANG, Aixing, GONG, Jian, TENG, Renhao, LI, Ruifeng
Format: Patent
Sprache:eng
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Zusammenfassung:A preparation method of glassless grain-oriented silicon steel includes the following operations. During a decarburization annealing, a thickness of an oxide film on a surface of strip is 1.5-2.5 μm; an atomic weight ratio of Si element and Fe element in the oxide film satisfies: Si/(Si+Fe)≥0.76; during a high-temperature annealing, a cooling stage includes sequentially: cooling with an inner cover when a temperature drops from 1200° C. to 500° C.; wherein a protective gas is a mixed gas containing nitrogen and hydrogen, and a volume percentage of the hydrogen in the mixed gas is >3%; cooling with the inner cover when the temperature drops from 500° C. to 200° C.; wherein the protective gas is nitrogen; and cooling in air by removing the inner cover when the temperature is