METHODS FOR PRODUCING A COMPOSITION WITH A FERROELECTRIC PEROVSKITE PRIMARY PHASE AND A TUNABLE SECONDARY CRYSTALLINE PHASE OF RELAXOR-DIELECTRIC, ASSOCIATED COMPOSITIONS, AND ASSOCIATED DEVICES

A method that incorporates teachings of the subject disclosure may comprise, for example, selecting a barium-strontium-titanate (BST) material, wherein the BST material has a perovskite lattice structure with at least a first lattice constant and a second lattice constant; selecting a strontium-barium-niobate (SBN) material, wherein the SBN material has a lattice structure with at least a third lattice constant and a fourth lattice constant, wherein the third lattice constant is substantially equal to the first lattice constant, and wherein the fourth lattice constant is substantially equal to the second lattice constant; and growing, on a grain boundary region of the BST material, the SBN material, wherein the growing is via self-assembly, and wherein the growing is facilitated by the third lattice constant of the SBN material being substantially equal to the first lattice constant and the fourth lattice constant of the SBN material being substantially equal to the second lattice constant. Other embodiments are disclosed.