On-Line Adjustment of Mixed Catalyst Ratio and Olefin Polymerization

The present disclosure provides processes for polymerizing olefin(s). In at least one embodiment, a method for producing a polyolefin is provided. The method includes contacting a first composition and a second composition in a line to form a third composition. The first composition includes a conta...

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Hauptverfasser: Holtcamp, Matthew W, Harlan, Charles J, Ye, Xuan, Stevens, Kevin A, Sanders, David F, Silva, Adriana S, Olson, Joshua P, Bedoya, Matthew S
Format: Patent
Sprache:eng
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Zusammenfassung:The present disclosure provides processes for polymerizing olefin(s). In at least one embodiment, a method for producing a polyolefin is provided. The method includes contacting a first composition and a second composition in a line to form a third composition. The first composition includes a contact product of a first catalyst, a second catalyst, a support, a first activator, and a diluent, and the mol ratio of first catalyst to second catalyst is from 90:10 to 40:60. The second composition includes a contact product of the second catalyst, a second activator, and a second diluent. The third composition includes a mol ratio of first catalyst to second catalyst of from 89:11 to 10:90. The method includes introducing the third composition from the line into a gas-phase fluidized bed reactor, exposing the third composition to polymerization conditions, and obtaining a polyolefin.