METHOD FOR PREPARING A UV CURABLE COATING COMPOSITION

The present invention relates to a method comprising the steps of: a) contacting an acrylate monomer, a carboxylic acid monomer, and a chain transfer agent under free radical polymerization conditions to form a solution of a polymer having an Mn in the range of from 5,000 to 50,000 Daltons; b) conta...

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Bibliographische Detailangaben
Hauptverfasser:	Hejl, Andrew, Hegedus, Charles R, Ladewski, Rebecca L, Vogel, Erin B, Wang, Wenqin, Greyson, Eric C
Format:	Patent
Sprache:	eng
Schlagworte:	APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL CHEMISTRY COMPOSITIONS BASED THEREON MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS METALLURGY ORGANIC MACROMOLECULAR COMPOUNDS PERFORMING OPERATIONS PROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TOSURFACES, IN GENERAL SPRAYING OR ATOMISING IN GENERAL THEIR PREPARATION OR CHEMICAL WORKING-UP TRANSPORTING
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Beschreibung
Zusammenfassung:	The present invention relates to a method comprising the steps of: a) contacting an acrylate monomer, a carboxylic acid monomer, and a chain transfer agent under free radical polymerization conditions to form a solution of a polymer having an Mn in the range of from 5,000 to 50,000 Daltons; b) contacting the solution with a base and an ethylenically unsaturated glycidyl functionalized monomer to form a solution of an ethylenically unsaturated acrylate polymer; c) contacting the solution of the ethylenically unsaturated functionalized acrylate polymer with water to form an aqueous dispersion of ethylenically unsaturated functionalized acrylate polymers; and d) removing the organic solvent. The method of the present invention provides a composition suitable for use as a UV curable coating that achieves an excellent balance of hardness, flexibility, and warmth with less reliance on costly MFAs.