Methods To Prepare Catalysts For In-Line Bulk Polymerization

A method is described for the formation of an active catalyst system for use in the in-line bulk polymerization of polydienes. The method provides a homogeneous, active catalyst system which is capable of being transported to a polymerization reactor for use without causing blockages in piping, thereby saving time and production costs. The catalyst system is formed in-line in a continuous method to avoid prolonged storage periods of the catalyst that can otherwise lead to degradation and disposal of the aged catalyst system.