TETRADENTATE ORGANIC LIGAND H3-MN-16Bn CONTAINING LONG ALKYL GROUP, PRECURSOR THEREOF, AND METHOD FOR PREPARING THE SAME

TETRADENTATE ORGANIC LIGAND H3-MN-16Bn CONTAINING LONG ALKYL GROUP, PRECURSOR THEREOF, AND METHOD FOR PREPARING THE SAME

A tetradentate organic ligand H3-MN-16Bn containing a long alkyl group, a precursor thereof, and a method for preparing the same are revealed. A precursor of H3-MN-16Bn, benzyl 16-bromohexadecanate, is obtained by esterification reaction of 16-bromohexadecanoic acid. Then bimolecular nucleophilic su...

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Bibliographische Detailangaben
Hauptverfasser: HSU CHENG-FANG, TSAI JIA-DONG, CHANG YU, LU KUEI-LIN
Format: Patent
Sprache:eng
Schlagworte:
ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
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Zusammenfassung:A tetradentate organic ligand H3-MN-16Bn containing a long alkyl group, a precursor thereof, and a method for preparing the same are revealed. A precursor of H3-MN-16Bn, benzyl 16-bromohexadecanate, is obtained by esterification reaction of 16-bromohexadecanoic acid. Then bimolecular nucleophilic substitution reaction (SN2) of Benzyl 16-bromohexadecanate with nitrogen sulfide (N2S2) is carried out to get H3-MN-16Bn that is used as a standard hydrolysis metabolites of non-radioactive 185Re-complex compound.