ELECTROCHEMICAL CELLS WITH IMPROVED SPIRAL-WOUND ELECTRODE ASSEMBLY

A spiral-wound electrode assembly, an electrochemical cell with the spiral-wound electrode assembly, and a method of manufacturing an electrochemical cell with the spiral-wound electrode assembly are disclosed. The spiral-wound electrode assembly has a first electrode that has a first electrode active material, a leading edge and a trailing edge. The assembly has a second electrode that includes a second electrode active material, a leading edge and a trailing edge. A separator is located between the first electrode and the second electrode. The electrode assembly has an interfacial anode-to-cathode ratio of less than about 1.2. The first electrode, second electrode, and separator are wound so that the first electrode forms a layer at the outermost radius of the electrode assembly and so that the trailing edge of the second electrode extends past the trailing edge of the first electrode.