NOx SENSING MATERIALS AND SENSORS INCORPORATING SAID MATERIALS

Gas-sensitive materials are disclosed which are mixtures or composites of BaSnO3, and another component comprising one or more phases from the group: CuO, Cr2O3, Fe2O3, MnO, NiO, CoO, Bi2O3, Sb2O3, Sb2O5, WO3, ZnO, and SnO2. The mixture may be modified further by the addition in a highly dispersed m...

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Bibliographische Detailangaben
Hauptverfasser: SMITH PETER, CAVANAGH LEON
Format: Patent
Sprache:eng
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Beschreibung
Zusammenfassung:Gas-sensitive materials are disclosed which are mixtures or composites of BaSnO3, and another component comprising one or more phases from the group: CuO, Cr2O3, Fe2O3, MnO, NiO, CoO, Bi2O3, Sb2O3, Sb2O5, WO3, ZnO, and SnO2. The mixture may be modified further by the addition in a highly dispersed manner of fine (less than about 20 nm) particulates of precious metals (Pt, Pd, Au, Ag) to enhance performance. Advantages include: (a) sensitivity in the range 1-2500 ppm NOx typical of combustion environments, (b) reduced humidity influence, (c) repeatability and reliability, and (d) baseline stability over time. In one embodiment, the material includes a mixture of BaSnO3 and CuO such that CuO is present at 25-50 mol %.