Process for Hydrogen Peroxide Production Including Step for Regeneration of Working Solution

Provided is a provides a method for producing hydrogen peroxide, comprising a step of reducing and then oxidizing a working solution containing an organic solvent, anthraquinone having an alkyl substituent, and tetrahydroanthraquinone having an alkyl substituent to produce hydrogen peroxide; and a working solution regeneration step of removing an inert substance, generated as a sub product by the production of hydrogen peroxide, from the working solution and re-circulating the working solution deprived of the inert substance back into the step of producing hydrogen peroxide; wherein the working solution regeneration step includes i) a first distillation step of recovering the organic solvent by distillation performed at an atmospheric or a lower pressure; and ii) a second distillation step of, following the first distillation step, recovering the anthraquinone and the tetrahydroanthraquinone by distillation performed at a still lower pressure at 200° C. or higher for a residence time of 1 hour or longer.