212Bi or 213Bi Generator from supported parent isotope

The invention includes a radionuclide generator having an ion exchange sorbent that comprises oxygen-containing functional groups grafted by organic linking groups to an inorganic oxygen-linked network and a parent isotope. For 212Bi or 213Bi generators, the parent isotope may be 224Ra, 225Ra or 225...

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Hauptverfasser: CISAR ALAN J, GALI HARIPRASAD
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creator CISAR ALAN J
GALI HARIPRASAD
description The invention includes a radionuclide generator having an ion exchange sorbent that comprises oxygen-containing functional groups grafted by organic linking groups to an inorganic oxygen-linked network and a parent isotope. For 212Bi or 213Bi generators, the parent isotope may be 224Ra, 225Ra or 225Ac. The surface area of the sorbent is preferably less than about 10 m2/g and more preferably less than about 1 m2/g. The exchange sorbent may be formed of any covalently bonded inorganic oxide that is capable of forming oxygen-linked networks. The oxidized functional groups may include sulfonato groups, may include moieties selected from -SO3H, -SO3Na, -SO3K, -SO3Li, -SO3NH4 or may include moieties selected from -PO(OX)2 or -COOX, wherein X is selected from H, Na, K or NH4 or combinations thereof. A 213Bi or 212Bi generator process includes eluting 213Bi or 212Bi with an aqueous solvent that includes 225Ac or 225Ra or 224Ra on the above support medium.
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For 212Bi or 213Bi generators, the parent isotope may be 224Ra, 225Ra or 225Ac. The surface area of the sorbent is preferably less than about 10 m2/g and more preferably less than about 1 m2/g. The exchange sorbent may be formed of any covalently bonded inorganic oxide that is capable of forming oxygen-linked networks. The oxidized functional groups may include sulfonato groups, may include moieties selected from -SO3H, -SO3Na, -SO3K, -SO3Li, -SO3NH4 or may include moieties selected from -PO(OX)2 or -COOX, wherein X is selected from H, Na, K or NH4 or combinations thereof. 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subjects CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM,CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THERARE-EARTH METALS
CONVERSION OF CHEMICAL ELEMENTS
INORGANIC CHEMISTRY
METALLURGY
NUCLEAR ENGINEERING
NUCLEAR PHYSICS
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
PHYSICS
RADIOACTIVE SOURCES
THEIR RELEVANT APPARATUS
TRANSPORTING
title 212Bi or 213Bi Generator from supported parent isotope
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