Process for selective hydrodesulfurization of naphtha

A process for the selective hydrodesulfurization of a naphtha containing olefins and organosulfur compounds is disclosed, which minimizes the hydrogenation of the olefins and results in a product with a low sulfur content. The process involves a two-stage hydrodesulfurization with H2S removed from t...

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Bibliographische Detailangaben
Hauptverfasser:	DUARTE MARCUS V.E, GOMES JEFFERSON R, STUART GIANE R, DE ALMEIDA RAFAEL M, ODDONE ROGERIO, PACHECO MARCELO E
Format:	Patent
Sprache:	eng
Schlagworte:	CHEMISTRY CRACKING HYDROCARBON OILS FUELS LUBRICANTS METALLURGY MINERAL WAXES PEAT PETROLEUM, GAS OR COKE INDUSTRIES PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS REFORMING OF NAPHTHA TECHNICAL GASES CONTAINING CARBON MONOXIDE
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Beschreibung
Zusammenfassung:	A process for the selective hydrodesulfurization of a naphtha containing olefins and organosulfur compounds is disclosed, which minimizes the hydrogenation of the olefins and results in a product with a low sulfur content. The process involves a two-stage hydrodesulfurization with H2S removed from the first stage effluent. A flow of hydrogen and at least one added non-reactive compound is fed into the first stage, wherein the H2 molar fraction ranges from 0.2 to 1.0, and with H2S at the reactor intake limited to a maximum of 0.1% by volume. The second stage involves a feedstream of hydrogen and at least one added non-reactive compound, wherein the H2 molar fraction ranges from 0.2 to 0.7 and with H2S at the reactor intake limited to a maximum of 0.05% by volume.