Coating compositions which contain a low surface tension (meth) acrylate containing block copolymer flow control agent

A thermosetting composition that includes a first reactant having functional groups; a second reactant having functional groups coreactive with the functional groups of the first reactant; and a block copolymer flow control agent. The block copolymer includes a first block made up of residues of a r...

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Bibliographische Detailangaben
Hauptverfasser: SMITH JOANNE H, GOETZ JONATHAN D, BARKAC KAREN A, SCHIMMEL KARL F, COCA SIMION, HUMBERT KURT A
Format: Patent
Sprache:eng
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Beschreibung
Zusammenfassung:A thermosetting composition that includes a first reactant having functional groups; a second reactant having functional groups coreactive with the functional groups of the first reactant; and a block copolymer flow control agent. The block copolymer includes a first block made up of residues of a radically polymerizable fluoroalkyl (meth)acrylate monomer, a second block made up of residues of a second radically polymerizable ethylenically unsaturated monomer, and optionally a third block made up of residues of a third radically polymerizable ethylenically unsaturated monomer. The first, second and third blocks are made of different residues from each other and the block copolymer has a polydispersity index of less than 2.5. Also disclosed is a method of coating a substrate including the steps of applying the present thermosetting composition to the substrate; coalescing the thermosetting composition to form a substantially continuous film; and curing said thermosetting composition by the application of heat.