Catalytic compositions for the oxidation of substrates

Catalytic compositions and sequential catalytic methods are generally described. In some embodiments, a composition comprises a first catalyst comprising a Cu-modified zeolite, and a second catalyst capable of a coupling reaction between (a) an intermediate resulting from a reaction of a reactant at...

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Hauptverfasser: Román-Leshkov, Yuriy, Serna Merino, Pedro M, Dinh, Kimberly, Meyer, Randall J, Sullivan, Mark
Format: Patent
Sprache:eng
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Zusammenfassung:Catalytic compositions and sequential catalytic methods are generally described. In some embodiments, a composition comprises a first catalyst comprising a Cu-modified zeolite, and a second catalyst capable of a coupling reaction between (a) an intermediate resulting from a reaction of a reactant at the first catalyst, and (b) a co-reagent, wherein a rate of diffusion of the co-reagent within one or more cages and/or pores of the first catalyst is lower than a rate of diffusion of the intermediate within the one or more cages and/or pores of the first catalyst.