Lithium complex oxide

A lithium complex oxide includes a mixture of first particles of n1 (n1>40) aggregated primary particles and second particles of n2 (n2≤20) aggregated primary particles, the lithium complex oxide represented by Chemical Formula 1 and having FWHM (deg., 2θ) of 104 peak in XRD, defined by a hexagon...

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Bibliographische Detailangaben
Hauptverfasser:	Lee, Jung Han, Choi, Seung Woo, Bae, Joong Ho, Suh, Jun Won, Choi, Kwang Seok, Son, Jin Oh, Choi, Moon Ho, Yun, Jin Kyeong, Yun, Mi Hye
Format:	Patent
Sprache:	eng
Schlagworte:	BASIC ELECTRIC ELEMENTS CABLES CHEMISTRY COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSESC01D OR C01F CONDUCTORS ELECTRICITY INORGANIC CHEMISTRY INSULATORS METALLURGY PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING ORDIELECTRIC PROPERTIES
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Beschreibung
Zusammenfassung:	A lithium complex oxide includes a mixture of first particles of n1 (n1>40) aggregated primary particles and second particles of n2 (n2≤20) aggregated primary particles, the lithium complex oxide represented by Chemical Formula 1 and having FWHM (deg., 2θ) of 104 peak in XRD, defined by a hexagonal lattice having R-3m space group, in a range of Formula 1:LiaNixCoyMnzM1-x-y-zO2, [Chemical Formula 1]where M is selected from: B, Ba, Ce, Cr, F, Mg, Al, Cr, V, Ti, Fe, Zr, Zn, Si, Y, Nb, Ga, Sn, Mo, W, P, Sr, and any combination thereof, 0.9≤a≤1.3, 0.6≤x≤1.0, 0.0≤y≤=0.4, 0.0≤z≤0.4, and 0.0≤1-x-y-z≤0.4,−0.025≤FWHM(104)−{0.04+(xfirst particle−0.6)×0.25}≤0.025, [Formula 1]where FWHM(104) is represented by Formula 2,FWHM(104)={(FWHMChemical Formula 1 powder(104)−0.1×mass ratio of second particles)/mass ratio of first particles}−FWHMSi powder (220). [Formula 2]