Wettability estimation using magnetic resonance

A method of estimating a wettability characteristic of a rock and fluid system includes acquiring a sample of the rock material, performing a first nuclear magnetic resonance (NMR) measurement of the sample when the sample is in a full water saturation condition, and measuring a first T2 distribution, performing a second NMR measurement of the sample when the sample is in a second partial saturation condition, and measuring a second T2 distribution. The method also includes separating a hydrocarbon component of the second T2 distribution from a water component of the second T2 distribution, applying a fluid substitution model to the water component of the second T2 distribution to generate a computed T2 distribution, and calculating a wettability index (WI) based on a difference between the first T2 distribution and the computed T2 distribution.