Metal-organic framework for adsorptive separation of acetylene/ethylene mixture and preparation method therefor

Metal-organic framework for adsorptive separation of acetylene/ethylene mixture and preparation method therefor

The present invention provides a metal-organic framework material for the adsorptive separation of acetylene/ethylene mixture and preparation method therefor. The metal-organic framework material is named TJE-2 with a chemical formula of [Ni(pyc)(apyz)]n, wherein, Ni represents nickel as a metal cen...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: Huang, Hengcong, Gu, Yifan, Li, Fengting, Wang, Ying
Format: Patent
Sprache:eng
Schlagworte:
ACYCLIC OR CARBOCYCLIC COMPOUNDS
ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
SEPARATION
THEIR RELEVANT APPARATUS
TRANSPORTING
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Beschreibung
Zusammenfassung:The present invention provides a metal-organic framework material for the adsorptive separation of acetylene/ethylene mixture and preparation method therefor. The metal-organic framework material is named TJE-2 with a chemical formula of [Ni(pyc)(apyz)]n, wherein, Ni represents nickel as a metal center, pyc represents the organic ligand 1H-pyrazole-4-carboxylic acid, and apyz represents the organic ligand 2-aminopyrazine. The preparation method is as follows: thoroughly dissolving pyc, apyz and Ni(NO3)2·6H2O, transferring the mixture to a pressure-resistant closed container for heating reaction, followed by solvent exchange and activation to obtain a homogeneous powder material. The ultra-microporous metal-organic framework material prepared by the present invention features a significantly high C2H2 adsorption capacity, good selectivity, and low raw material costs, and therefore can realize C2H2/C2H4 separation at lower costs.