Preparation method of mesoporous Fe-Cu-SSZ-13 molecular sieve

A method of preparing a mesoporous Fe-Cu-SSZ-13 molecular sieve includes activating an aluminum source, a silicon source, an iron source and a copper source respectively; mixing the activated minerals with sodium hydroxide, water and a seed crystal at 25-90° C., while controlling feeding amounts of...

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Hauptverfasser:	Cui, Qingyan, Yue, Yuanyuan, Bao, Xiaojun, Wang, Tinhai, Zhu, Haibo, Bai, Zhengshuai, Liu, Ben, Liu, Jie, Yuan, Pei, Lv, Nangui
Format:	Patent
Sprache:	eng
Schlagworte:	CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY COMPOUNDS THEREOF INORGANIC CHEMISTRY METALLURGY NON-METALLIC ELEMENTS PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL SEPARATION THEIR RELEVANT APPARATUS TRANSPORTING
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Zusammenfassung:	A method of preparing a mesoporous Fe-Cu-SSZ-13 molecular sieve includes activating an aluminum source, a silicon source, an iron source and a copper source respectively; mixing the activated minerals with sodium hydroxide, water and a seed crystal at 25-90° C., while controlling feeding amounts of respective raw materials so that molar ratios of respective materials in a synthesis system are as follows: SiO2/Al2O3=10-100, SiO2/Fe2O3=30-3000, SiO2/CuO=1-100, Na2O/SiO2=0.1-0.5, H2O/SiO2=10-50, template/SiO2=0.01-0.5; adding an acid source to adjust pH of the system for first aging; and adding the acid source again to adjust the pH of the system for second aging to obtain aged gel; pouring an aged mixture into a kettle; cooling a crystallized product and filtering to remove a liquor; washing a filter cake; drying to obtain a solid; performing ion exchange; and filtering, washing and drying the solid to obtain powder; and placing the powder in a muffle furnace.