Process for converting cyclic alkylene ureas into their corresponding alkylene amines

A process is provided for converting one or more cyclic ethylene ureas into corresponding ethylene amines and carbon dioxide. The process may include contacting water with one or more cyclic alkylene urea compounds comprising one or more cyclic alkylene urea moieties in a reaction vessel at a temper...

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Bibliographische Detailangaben
Hauptverfasser: Kantzer, Eike Nicolas, Ehlers, Ina, Veneman, Rens, Raaijmakers, Michiel Jozef Thomas, Ten Kate, Antoon Jacob Berend, Edvinsson, Rolf Krister, Van Dam, Hendrik, Jovic, Slavisa, Wernersson, Stig Mikael, Lake, Karl Fredrik
Format: Patent
Sprache:eng
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Zusammenfassung:A process is provided for converting one or more cyclic ethylene ureas into corresponding ethylene amines and carbon dioxide. The process may include contacting water with one or more cyclic alkylene urea compounds comprising one or more cyclic alkylene urea moieties in a reaction vessel at a temperature of 150 to 400° C., optionally in the presence of an amine compound selected from the group of primary amines, cyclic secondary amines and bicyclic tertiary amines. The mole ratio of water to cyclic alkylene urea moieties is in the range of from about 0.1 to about 20. In the reaction, at least a portion of the cyclic alkylene urea moieties are converted to corresponding alkylenediamine moieties and carbon dioxide. The process may further include removing the carbon dioxide from the liquid reaction mixture in a stripping vessel by feeding a stripping fluid to the stripping vessel. Further, the process may include removing a carbon dioxide-containing stripping fluid.