Lubricant treatments for free-radical polymerizations

A process to prepare an ethylene-based polymer, said process comprising polymerizing a mixture comprising ethylene, at a pressure greater than, or equal to, 100 MPa, in the presence of at least one free-radical initiator; and in a reactor system comprising at least one reactor and at least one Hyper...

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Bibliographische Detailangaben
Hauptverfasser: Ewart, Sean W, Munjal, Sarat, Sun, Kefu
Format: Patent
Sprache:eng
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Zusammenfassung:A process to prepare an ethylene-based polymer, said process comprising polymerizing a mixture comprising ethylene, at a pressure greater than, or equal to, 100 MPa, in the presence of at least one free-radical initiator; and in a reactor system comprising at least one reactor and at least one Hyper-compressor, and wherein at least one oil formulation, optionally comprising one or more lubrication agents, is added to the Hyper-compressor; and wherein at least one of the following steps takes place: A) thermally treating the one or more lubrication agents, in an oxygen-free atmosphere, to achieve a peroxide level ≤10 ppm, based on the weight of the lubrication agent(s), and then adding said agent(s) to the oil formulation, prior to adding the oil formulation to the Hyper-compressor; or B) thermally treating the oil formulation, in an oxygen-free atmosphere, to achieve a peroxide level ≤10 ppm, based on the weight of the oil formulation, prior to adding the oil formulation to the Hyper-compressor; C) a combination of A and B.