Process for recovering para-xylene using a metal organic framework adsorbent in a simulated moving-bed process

Para-xylene is separated from a mixture of C8 aromatics using a simulated moving bed (SMB) adsorption process, wherein a MOF is used as an adsorbent and an alkane or alkene having 7 or less carbon atoms, such as hexane or heptane is used as desorbent. Because of the difference in boiling points of a...

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Hauptverfasser: Nair, Sankar, Rungta, Meha, Zhang, Ke, Pilliod, Dana L, Tinger, Robert G, Sholl, David, Gee, Jason, Abichandani, Jeevan S, Go, Anthony
Format: Patent
Sprache:eng
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Zusammenfassung:Para-xylene is separated from a mixture of C8 aromatics using a simulated moving bed (SMB) adsorption process, wherein a MOF is used as an adsorbent and an alkane or alkene having 7 or less carbon atoms, such as hexane or heptane is used as desorbent. Because of the difference in boiling points of a hexane or heptane desorbent as compared to conventional desorbents such as toluene or para-diethylbenzene, less energy is required to separate hexane or heptane from C8 aromatics by distillation than the energy required to separate toluene or diethylbenzene from C8 aromatics by distillation.